Pushing the glass transition towards random close packing using self-propelled hard spheres.

نویسندگان

  • Ran Ni
  • Martien A Cohen Stuart
  • Marjolein Dijkstra
چکیده

Although the concept of random close packing with an almost universal packing fraction of approximately 0.64 for hard spheres was introduced more than half a century ago, there are still ongoing debates. The main difficulty in searching the densest packing is that states with packing fractions beyond the glass transition at approximately 0.58 are inherently non-equilibrium systems, where the dynamics slows down with a structural relaxation time diverging with density; hence, the random close packing is inaccessible. Here we perform simulations of self-propelled hard spheres, and we find that with increasing activity the relaxation dynamics can be sped up by orders of magnitude. The glass transition shifts to higher packing fractions upon increasing the activity, allowing the study of sphere packings with fluid-like dynamics at packing fractions close to RCP. Our study opens new possibilities of investigating dense packings and the glass transition in systems of hard particles.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Amorphous packings of hard spheres in large space dimension

In a recent paper we derived an expression for the replicated free energy of a liquid of hard spheres based on the HNC free energy functional. An approximate equation of state for the glass and an estimate of the random close packing density were obtained in d = 3. Here we show that the HNC approximation is not needed: the same expression can be obtained from the full diagrammatic expansion of ...

متن کامل

ar X iv : c on d - m at / 0 60 15 73 v 1 2 5 Ja n 20 06 Amorphous packings of hard spheres in large space dimension

In a recent paper we derived an expression for the replicated free energy of a liquid of hard spheres based on the HNC free energy functional. An approximate equation of state for the glass and an estimate of the random close packing density were obtained in d = 3. Here we show that the HNC approximation is not needed: the same expression can be obtained from the full diagrammatic expansion of ...

متن کامل

The ideal glass transition of hard spheres.

We use the replica method to study the ideal glass transition of a liquid of identical hard spheres. We obtain estimates of the configurational entropy in the liquid phase, of the Kauzmann packing fraction phi(K), in the range of 0.58-0.62, and of the random close packing density phi(c), in the range of 0.64-0.67, depending on the approximation we use for the equation of state of the liquid. We...

متن کامل

Glass transition and random close packing above three dimensions.

Motivated by a recently identified severe discrepancy between a static and a dynamic theory of glasses, we numerically investigate the behavior of dense hard spheres in spatial dimensions 3 to 12. Our results are consistent with the static replica theory, but disagree with the dynamic mode-coupling theory, indicating that key ingredients of high-dimensional physics are missing from the latter. ...

متن کامل

Do binary hard disks exhibit an ideal glass transition?

We demonstrate that there is no ideal glass transition in a binary hard-disk mixture by explicitly constructing an exponential number of jammed packings with densities spanning the spectrum from the accepted amorphous glassy state to the phase-separated crystal. Thus the configurational entropy cannot be zero for an ideal amorphous glass, presumed distinct from the crystal in numerous theoretic...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Nature communications

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2013